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| 16.09.2006 | 22:00 | Deportivo La Coruña | - | Villarreal CF | 2:0 (1:0) | |
| 17.09.2006 | 19:00 | Sevilla FC | - | Real Betis | 3:2 (1:1) | |
| 20:00 | Real Zaragoza | - | RCD Mallorca | 2:0 (0:0) | ||
| 20:00 | Recreativo Huelva | - | Levante UD | 0:1 (0:0) | ||
| 20:00 | Athletic Bilbao | - | Atlético Madrid | 1:4 (0:2) | ||
| 20:00 | Valencia CF | - | Getafe CF | 2:0 (1:0) | ||
| 20:00 | Racing Santander | - | FC Barcelona | 0:3 (0:1) | ||
| 20:00 | CA Osasuna | - | Gimnàstic de Tarragona | 2:0 (1:0) | ||
| 20:00 | Espanyol | - | Celta de Vigo | 2:1 (0:0) | ||
| 21:00 | Real Madrid | - | Real Sociedad | 2:0 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sevilla FC | 3 | 3 | 0 | 0 | 10:3 | 7 | 9 |
| 2 |
|
Valencia CF | 3 | 3 | 0 | 0 | 5:1 | 4 | 9 |
| 3 |
|
FC Barcelona | 3 | 3 | 0 | 0 | 9:2 | 7 | 9 |
| 4 |
|
Deportivo La Coruña | 3 | 2 | 1 | 0 | 5:2 | 3 | 7 |
| 5 |
|
Real Madrid | 3 | 2 | 1 | 0 | 6:1 | 5 | 7 |
| 6 |
|
Real Zaragoza | 3 | 2 | 0 | 1 | 7:3 | 4 | 6 |
| 7 |
|
Atlético Madrid | 3 | 2 | 0 | 1 | 5:2 | 3 | 6 |
| 8 |
|
Getafe CF | 3 | 2 | 0 | 1 | 3:2 | 1 | 6 |
| 9 |
|
Recreativo Huelva | 3 | 1 | 1 | 1 | 2:2 | 0 | 4 |
| 10 |
|
Real Betis | 3 | 1 | 0 | 2 | 6:5 | 1 | 3 |
| 11 |
|
Celta de Vigo | 3 | 1 | 0 | 2 | 5:6 | -1 | 3 |
| 12 |
|
Gimnàstic de Tarragona | 3 | 1 | 0 | 2 | 2:4 | -2 | 3 |
| 13 |
|
CA Osasuna | 3 | 1 | 0 | 2 | 2:5 | -3 | 3 |
| 14 |
|
Levante UD | 3 | 1 | 0 | 2 | 2:8 | -6 | 3 |
| 15 |
|
Espanyol | 3 | 1 | 0 | 2 | 2:5 | -3 | 3 |
| 16 |
|
RCD Mallorca | 3 | 0 | 2 | 1 | 1:3 | -2 | 2 |
| 17 |
|
Villarreal CF | 3 | 0 | 1 | 2 | 0:3 | -3 | 1 |
| 18 |
|
Real Sociedad | 3 | 0 | 1 | 2 | 2:6 | -4 | 1 |
| 19 |
|
Athletic Bilbao | 3 | 0 | 1 | 2 | 2:8 | -6 | 1 |
| 20 |
|
Racing Santander | 3 | 0 | 0 | 3 | 0:5 | -5 | 0 |
